College students’love is a universal phenomenon.Values of love play a fundamental role in the establishment and experience of individual love relationship,Attachment affects the establishment of individual and other relationships.In order to understand the current situation and the relation between College Students’attachment and Values of Love,342 college students were investigated by using the questionnaire method. The results show that the attachment degree of students in this area, among which the fearful attachment dominates,is low;the values of love are mainly positive motivation and intrinsic criteria for spouse selection. Attachment avoidance is negatively correlated with positive motivation , while attachment anxiety is positively correlated with negative motivation. Further analysis shows that attachment can predict the scores of love values.